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A crystal structure (an arrangement of atoms in a crystal) is characterized by its unit cell, a small imaginary box containing one or more atoms in a specific spatial arrangement.

The unit cells are stacked in three-dimensional space to form the crystal.

In the final block of ice, each of the small crystals (called "crystallites" or "grains") is a true crystal with a periodic arrangement of atoms, but the whole polycrystal does not have a periodic arrangement of atoms, because the periodic pattern is broken at the grain boundaries.

One of the oldest techniques in the science of crystallography consists of measuring the three-dimensional orientations of the faces of a crystal, and using them to infer the underlying crystal symmetry. This is determined by the crystal structure (which restricts the possible facet orientations), the specific crystal chemistry and bonding (which may favor some facet types over others), and the conditions under which the crystal formed.

Some crystals have formed by magmatic and metamorphic processes, giving origin to large masses of crystalline rock.

Other crystalline rocks, the metamorphic rocks such as marbles, mica-schists and quartzites, are recrystallized.

This means that they were at first fragmental rocks like limestone, shale and sandstone and have never been in a molten condition nor entirely in solution, but the high temperature and pressure conditions of metamorphism have acted on them by erasing their original structures and inducing recrystallization in the solid state Specific industrial techniques to produce large single crystals (called boules) include the Czochralski process and the Bridgman technique.

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For example, selenite crystals in excess of 10 meters are found in the Cave of the Crystals in Naica, Mexico.[12] For more details on geological crystal formation, see above.

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